Isothermal Electrolysis: Technology Overview
How pulsed waveform architecture achieves >92% efficiency without platinum, iridium, or membranes
Abstract
This whitepaper introduces Tobe Energy's isothermal electrolysis architecture—a fundamentally different approach to water splitting that achieves >92% system efficiency while eliminating exotic materials. It covers measured performance, core architecture, reliability design, and validation status based on 1,000+ hours of prototype testing.
What You'll Learn
- →How pulsed waveform operation reduces overpotentials and waste heat
- →Why near-ambient (<30°C) operation simplifies system design
- →Measured efficiency: 94.7% electrical (LHV) at nominal operating point
- →Material approach: 304 SS construction, no platinum or iridium
- →Product scaling: Tobe-25 (25 kW) through Tobe-2500 (2.5 MW)
Technical evaluators, project developers, investors, and engineering teams assessing electrolyzer technologies.
Executive Summary
Tobe Energy has developed a fundamentally different approach to water electrolysis that achieves >92% electrical efficiency while eliminating the exotic materials, complex thermal management, and degradation mechanisms that constrain conventional electrolyzer technologies.
- •Key metrics from prototype testing:
- •94.7% electrical efficiency (LHV)
- •~75% projected CAPEX reduction vs. PEM
- •1,000+ hours tested
- •80,000+ estimated stack life (hours)
The Problem
Green hydrogen remains expensive primarily because electrolysis is inefficient. Electricity accounts for 60-80% of levelized hydrogen cost, yet conventional electrolyzers convert only 60-75% of input energy to hydrogen.
PEM Electrolyzers achieve good current density but require platinum-group metals and expensive proton-exchange membranes. Membrane degradation limits lifetime. Iridium scarcity constrains scale-up.
Alkaline Electrolyzers avoid PGMs but require concentrated caustic electrolyte (25-40% KOH), creating safety, handling, and corrosion challenges. Limited turndown capability makes them poorly suited for variable renewable power.
Both technologies operate at elevated temperatures (60-90°C) and generate substantial waste heat—this isn't incidental, it's fundamental to how they work.
What Tobe Is
Tobe is a category-level rethink of water electrolysis. Rather than incremental improvements to PEM or alkaline systems, we've developed a fundamentally different electrochemical architecture.
- •Core subsystems:
- •Power Electronics: Converts input to controlled pulse waveforms using proprietary patterns
- •Electrolysis Module: Membrane-free design using 304 SS construction
- •Gas Handling: Simplified separation (no membrane → cleaner streams)
- •Key differentiators:
- •No Membranes — zero proton-exchange membrane
- •No Caustic — works with dilute or pure water
- •No PGMs — zero platinum or iridium
- •Near Ambient — operates <30°C, no active cooling
Performance
All figures represent measured system performance, not theoretical or stack-only values. We report LHV efficiency as the industry standard.
- •Electrical Efficiency (LHV): 94.7% — Stack performance at nominal operating point
- •System Efficiency: ~42.23 kWh/kg H₂ — Including power electronics and gas handling
- •Turndown Range: 10–100% — Maintains efficiency across operating range
- •Response Time: <1 second — Grid-following capability for renewable integration
- •Startup Time: Immediate — No warm-up period required
- •Operating Pressure: Up to 350 psig — Reduces downstream compression
- •Operating Temperature: <30°C — Near-ambient, minimal thermal management
- •Ambient Range: -30°C to +50°C — Outdoor installation without climate control
- •H₂ Purity: >99% — Higher purity available with standard PSA
Reliability
Tobe's architecture eliminates the primary failure modes that limit conventional electrolyzer lifetime. Nothing in the stack gets "used up" during operation.
- •Failure modes eliminated:
- •Membrane Degradation — No membrane in system
- •Catalyst Poisoning — No catalysts required
- •Thermal Cycling Fatigue — Isothermal operation
- •Caustic Corrosion — Dilute/neutral electrolyte
- •Electrode Degradation — Low-temp with corrosion-resistant 304 SS
- •Design philosophy:
- •Commodity materials — 304 SS uses globally available supply chains
- •Modular architecture — Individual cells serviceable without system shutdown
- •No single points of failure — Redundant sensing and control throughout
- •Industrial standards — Components selected for proven reliability
Scaling Approach
Tobe systems scale through modular multiplication of proven cell designs.
- •Product line:
- •Tobe-25: 25 kW, ~12 kg/day, compact skid — Distributed, pilot, R&D
- •Tobe-250: 250 kW, ~120 kg/day, 20' container — Commercial, fleet fueling
- •Tobe-2500: 2.5 MW, ~1,200 kg/day, multi-container — Industrial, hub-scale
- •Manufacturing economics:
- •Prototype cost: ~$446/kW (includes NRE and low-volume inefficiencies)
- •Projected at scale: ~$177/kW (at MW-scale volumes)
Conventional PEM electrolyzers cost $700–1,200/kW at scale. Tobe's projected $177/kW represents ~75% reduction from PEM.